It is harmful if swallowed. Dimethyl sulfate is miscible with organic solvents, and moderately soluble in water. Biologically Active Compounds | . Dimethyl Sulfate is an effective and widely used probe for sequence-specific protein-DNA interactions: Dangerous Goods Info: This compound is forbidden to ship by air under IATA regulations. ), ADR/RID: 6.1 (For reference only, please check. Wear face shield or eye protection in combination with breathing protection. It hydrolyzes readily in contact with water or moist surfaces to form monomethyl sulfate and -K!xb=$g{lm'[kC]o)u{ uFn5oR>+[p7Hx'y|>ll~9B/l`A7E{@ 0 hG"|reAQ^XY01( YxrJhM^#~%_zgq!+|QxC^5b&J}=Y] 3H"Q0qHf$&C,@3N:ct 802p}A(c([pW} ^ CPE:}7)5OhkBXA_? H314 Causes severe skin burns and eye damage, H317 May cause an allergic skin reaction, H341 Suspected of causing genetic defects. Repeated or prolonged inhalation of the vapour may cause effects on the lungs. See Notes. Odor: Almost odorless . x?1|wKl [ 1] Identification Product Name Dimethyl sulfoxide Cat No. % [16], In industry dimethyl sulfide is produced by treating hydrogen sulfide with excess methanol over an aluminium oxide catalyst:[17]. Handling in a well ventilated place. The content is subject to change without prior notice.Reproduction or further distribution of this information may be subject to copyright protection. Handle as a possible carcinogen. Detected decomposition products are dimethyl sulfide, dimethyldisulfide, and, in smaller quantity, formaldehyde. 2 DMS is highly toxic, corrosive, and has carcinogenic, mutagenic, and teratogenic potential. Vapor Density 4.35 Specific Gravity 1.330 Solubility Soluble in water Partition coefficient; n-octanol/water No data available Autoignition Temperature 470 C / 878 F . divided suspended solids that do not require heating before ignition can >> Then store and dispose of according to local regulations. Based upon the hydrolysis of dimethyl sulfate in aqueous environments(1), adsorption to soil and leaching are not expected to be important processes(SRC). Dimethyl sulfide (DMS) | Dimethyl sulfide is the major biogenic, volatile sulfur compound that is released from the ocean to the atmosphere | Buy chemicals and reagents online from Sigma Aldrich . Avoid formation of dust and aerosols. 18H 2 O), Aluminum chloride (Al . [18][19], At pathologically dangerous concentrations, this is known as dimethylsulfidemia. What Generation is Your Sterility Testing Pump? Dimethyl sulfate is a colorless, oily liquid that is slightly soluble in water. 3 0 obj several hours. View Price and Availability. Containers can be triply rinsed (or equivalent) and Dimethyl sulphate Dimethylsulfaat [Dutch] Dimethylsulfat [German] [ACD/IUPAC Name] dimethylsulfate dimthylsulfate [French] dimetil monosolfato [Italian] Dimetilsolfato [Italian] More. DMS originates primarily from DMSP, a major secondary metabolite in some marine algae. 6 0 obj P271 Use only outdoors or in a well-ventilated area. Density: 1.3300g/mL: Color: Colorless: Assay Percent Range: 99+% Infrared Spectrum: Authentic: Molecular Formula: C2H6O4S: Linear Formula (CH 3) 2 SO 4: Packaging: Plastic bottle: Odorous substances in sewage can cause corrosion and erosion in drainage pipelines, and even lead to great harm to the human body and environments. Information on Registered Substances comes from registration dossiers which have been assigned a registration number. Slightly more decomposition, however, can be expected with the industrial grade material. Density 1.33 g/mL at 20Ca Melting point -27Ca Boiling point 188C with decompositiona Log K ow . PUGVIEW FETCH ERROR: 503 National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health DMSO is highly stable at temperatures below 150C. It is a breakdown product of dimethylsulfoniopropionate (DMSP), and is also produced by the bacterial metabolism of methanethiol. Derivatization of Acids for GC Analysis, Marcel Dekker, Inc., New York - Basel, 2001, 221. https://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:59050, ACD/Labs Percepta Platform - PhysChem Module, US Environmental Protection Agencys EPISuite, Compounds with the same molecular formula, Search Google for structures with same skeleton. MODERATE, WHEN EXPOSED TO HEAT OR FLAME.Pure DIMETHYL SULFATE and concentrated aqueous ammonia react extremely violently with one another, as is the case for tertiary organic bases, [NFPA 491M, 1991]. Free standard shipping with $35 orders. This generates fire and explosion hazard. Rest and medical observation are therefore essential. Class IIIA Combustible Liquid: Fl.P. Molecularly imprinted polymers with synthetic dummy template for simultaneously selective removal and enrichment of ginkgolic acids from Ginkgo biloba L. leaves extracts. Introduction to DMSO Physical Properties. Dimethyl sulfide is a water-insoluble flammable liquid that boils at 37 C (99 F) and has a characteristic disagreeable odor. 00120. Give plenty of water to drink. P284 [In case of inadequate ventilation] wear respiratory protection. Substance: Dimethyl sulfate (Methyl sulfate; DMS) CAS 77-78-1 . About Us | Genome sequencing, phylogeny and annotation Welcome to the ECHA website. Excellent Quality Low Price Wholesale And Retail Factory Sell Sodium Aluminum Sulfate , Find Complete Details about Excellent Quality Low Price Wholesale And Retail Factory Sell Sodium Aluminum Sulfate,Sodium Hydrogen Sulfite,Reducing Agent Food Antiseptics Bleacher,Nahso3 from Supplier or Manufacturer-Hainan Yanghang Industrial Co., Ltd. Symptoms may be delayed for several hours after inhalation or dermal exposure. This Website requires your browser to be JavaScript enabled. Me 2 SO 4 is mainly used as a methylating agent in organic synthesis.. of sulfuric acidsuch as dimethyl sulfate, MeOSO 2 OMe, and diethyl sulfate, EtOSO 2 OEt, made from the alcohols methanol and ethanol, respectively, as well as sulfur trioxide/sulfuric acidare important industrial chemicals used to introduce methyl (Me) and ethyl (Et) groups into organic molecules. ), IMDG: I (For reference only, please check. Dimethyl Sulfoxide (DMSO) is a highly polar and water miscible organic liquid. P308+P313 IF exposed or concerned: Get medical advice/attention. Purity . Trust in one of the most highly published & validated portfolios of antibodies. Material is normally stable even under fire exposure conditions and is not hazardously reactive with water. This substance is probably carcinogenic to humans. This website uses cookies to ensure you get the best experience on our websites. . Keep container tightly closed. with flue gas scrubbing. If dimethyl sulfate has entered a watercourse or contaminated soil or vegetation, advise the police and public authorities. Four THMs and six HAAs are regulated by seve Get all suppliers and price by the below link: Home | Sprays of 3% ammonia solution may be used to "knock down" the vapor over spillages. <> Toxicity is most common following inhalation of vapors or dermal exposure. Structure-seq can be performed both in vivo and in vi Trihalomethanes (THMs) and haloacetic acids (HAAs) are the two most prevalent classes of disinfection by-products (DBPs) that are present in treated water. ], Skin: Prevent skin contact Eyes: Prevent eye contact Wash skin: When contaminated Remove: When wet or contaminated Change: No recommendation Provide: Eyewash, Quick drench, NIOSH REL : Ca TWA 0.1 ppm (0.5 mg/m 3 ) [skin] See Appendix A OSHA PEL ? P321 Specific treatment (see on this label). The following sequence of reactions explains the formation of these decomposition products: DMSO is remarkably stable in the presence of most neutral or basic salts and bases. Liquid density (at boiling point) 735.2 kg/m 3: Pressure 1.013 bar. The existence of odors in drainage pipelines is one of the most prominent environmental problems that urban residents complain about nowadays. Dimethyl sulfate (DMS) is a strong methylating agent with superior reaction rates and higher yields than competitive products. Dimethyl sulfate ignites in contact with unheated barium chlorite, due to the rapid formation of unstable methyl chlorite. Find out more on how we use cookies. Both dimethyl and diethyl sulfate are highly toxic. Let us know if you have suggestions to improve this article (requires login). SDS details and previous versions (where available) Dimethyl Sulfate, Essentq Manufacturer Scharlab, S.L. Download SDS. DIMETHYL SULPHATE For Synthesis Sulfuric Acid Dimethyl Ester. Normally stable, but can become unstable at elevated temperatures and pressures (e.g. Grade For Synthesis. 98%. 0 C; 15 C; . Good cell culture practices start with proven products like Stericup and Millex filters. CAS#:91-23-6 nitroanisole . Lookchem Provide Cas 1264670-01- Basic information: structure,molecular formula,safety information, MSDS, technical documents, related articles, process route, Upstream and downstream products & more at Lookchem. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. 2.1 (vs air) vapor . THF was removed under reduced pressure and the aqueous residue was washed with EtOAc. Each user must establish appropriate procedures for off-loading, handling, and use of the product(s). ass: Standard non-polar; Column type: Capillary; CAS no: 77781; Active phase: Polydimethyl siloxanes; Data type: Normal alkane RI; Authors: Zenkevich, I.G., Encyclopedia of Chromatography. Dimethyl Sulfate is commonly used as a reagent for the methylation of phenols, amines, and thiols. Half-upright position. 1786]. : D139-1; D139-RS19; NC1115865 CAS No 67-68-5 Synonyms Methyl sulfoxide; DMSO Recommended Use Laboratory chemicals. Keep container tightly closed. Please upgrade your Internet Explorer to a newer version. Dimethyl sulfate has been reported to produce tumors in the offspring of rats exposed intravenously. Simultaneous quantification of trihalomethanes and haloacetic acids in cheese by on-line static headspace gas chromatography-mass spectrometry. Dicocoalkyl Dimethyl Ammonium Chloride CAS 61789-77-3 Dimethylammoniumchloride Description: CAS No. Flash point between 37.8 and 93.3 C (100 and 200 F). Continuerinsing. Articles of Dimethyl sulfate are included as well. Nanomaterial pour density; Nanomaterial photocatalytic activity; Nanomaterial radical formation potential; Nanomaterial catalytic activity; . density 1.333 g/mL at 25 C (lit.) Ideas for in situ odor control can be divided into two main categories: the elimination of odorous . #=0!w}S&!T7U/9s$5U]O~K%~ed>7ueY?*us6/Wn]/LfSG{q&^{Wz;Ec' SUvE9d"Mxx*?~:YfD3H%4;rhYh11=( HHCpqp8h mD#%Si)rZr Dimethyl sulphate (CH 3) 2 SO 4 (DMS) is a methylating agent used industrially in the synthesis of pharmaceuticals, dyestuffs, perfumes, and pesticides. A minimum odor threshold may not be derived. Not for medicinal, household or other use. The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. Corrosive on ingestion. Training programs and seminars designed for you. liquid. Must be moderately heated or exposed to relatively high An inventory should be kept, showing quantity of carcinogen & date it was acquired . Give one or two glasses of water to drink. diesel fuel. Rinse with plenty of water (remove contact lenses if easily possible). Merck KGaA, Darmstadt, Germany, 2014. Stable; combustible. Material Safety Data Sheet or SDS for Dimethyl sulfate 803071 from Merck for download or viewing in the browser. [9][10] The CLAW hypothesis suggests that in this manner DMS may play a role in planetary homeostasis. Collect leaking liquid in sealable containers. For example, it serves a displaceable ligand in chloro(dimethyl sulfide)gold(I). Stable; combustible. There is sufficient evidence for the carcinogenicity in experimental animals of dimethyl sulfate. Under standard conditions, Me 2 SO 4 is a colourless oily liquid with a slight onion-like odour (although smelling it would . Airgas USA, LLC and its affiliates 259 North Radnor-Chester Road Suite 100 Radnor, PA 19087-5283 1-610-687-5253 1-866-734-3438 SDS # :001104 Synonym :Methane, 1,1'-thiobis-; Methane, thiobis-; Dimethyl sulfide; Methyl sulfide . ), IATA: DIMETHYL SULPHATE (For reference only, please check. Use powder, foam, carbon dioxide, water spray. CSID:6252, http://www.chemspider.com/Chemical-Structure.6252.html (accessed 09:35, Mar 18, 2023), Validated by Experts, Validated by Users, Non-Validated, Removed by Users, Predicted data is generated using the ACD/Labs Percepta Platform - PhysChem Module, Predicted data is generated using the US Environmental Protection Agencys EPISuite, Click to predict properties on the Chemicalize site, For medical information relating to Covid-19, please consult the. endobj JJJ8)D-XX It reduces the intermediate trioxolane. 1907/2006(REACH) . DIMETHYL SULFATE. ]Aa=+rj(~. Catalogs and product finders. Dimethyl sulphate EC Number: 201-058-1 EC Name: Dimethyl sulphate CAS Number: 77-78-1 Molecular formula: C2H6O4S IUPAC Name: dimethyl sulfate . Dimethyl Sulfate is a diester of methanol and sulfuric acid. Remove contaminated clothes. 98%. This condition is associated with blood borne halitosis and dimethylsulfiduria.[20][21][22]. Air - Density, Specific Weight and Thermal Expansion Coefficient vs. Catalog Number 803071 Product Name Dimethyl sulfate Do NOT induce vomiting. ambient temperature before ignition can occur and multiple finely Dimethyl sulphate MSDS Section 1: Chemical Product and Company Identification Product Name: Dimethyl sulphate Catalog Codes: 10604 CAS#: 77-78-1 RTECS: WS8225000 TSCA: TSCA 8(b) inventory: Dimethyl sulphate CI#: Not available. Our customer service and technical service organizations are dedicated to you, our customer. Some reports claim that DMS has a low olfactory threshold that varies from 0.02 to 0.1ppm between different persons, but it has been suggested that the odor attributed to dimethyl sulfide may in fact be due to disulfides, polysulfides and thiol impurities, since the odor of dimethyl sulfide is much less disagreeable after it is freshly washed with saturated aqueous mercuric chloride. Synonym : DMF; Dimethyl Formamide Chemical Name : N,N-Dimethylformamide Chemical Formula : HCON(CH3)2 COMPANY IDENTIFICATION Supplier: Pon Pure Chemicals Group CHENNAI, TAMILNADU, INDIA 24 Hour Health . Uses advised against Food, drug, pesticide or biocidal product use. Rinse and then wash skin with water and soap. Further oxidation affords dimethyl sulfone. Inhalation: LC50 Guinea pig inhalation 167 mg/cu m (32 ppm)/60 min. Depending on the degree of exposure, periodic medical examination is suggested. http://www.echemportal.org/echemportal/index?pageID=0&request_locale=en, CAMEO Chemicals, website: http://cameochemicals.noaa.gov/search/simple, ChemIDplus, website: http://chem.sis.nlm.nih.gov/chemidplus/chemidlite.jsp, ERG - Emergency Response Guidebook by U.S. Department of Transportation, website: Polymeric Microspheres and Magnetic Beads, Novabiochem Peptide and DNA Synthesis Reagents, Analytics and Sample Preparation Services, BioReliance Cell and Gene Therapy Testing Services, Calibration, Verification and Suitability Testing, Process Solutions: Portfolio Announcements. P260 Do not breathe dust/fume/gas/mist/vapours/spray. Product code SU0119 Revision date A harmful contamination of the air can be reached rather quickly on evaporation of this substance at 20C. Continue rinsing. It is essentially odorless, and has a low level of toxicity. DOI: 10.1016/J.ELECTACTA.2006.04.037 Corpus ID: 97063832; Electro-oxidation of dimethyl ether on Pt/C and PtMe/C catalysts in sulfuric acid @article{Liu2006ElectrooxidationOD, title={Electro-oxidation of dimethyl ether on Pt/C and PtMe/C catalysts in sulfuric acid}, author={Yan Liu and Shigenori Mitsushima and Kensuke Ota and Nobuyuki Kamiya}, journal={Electrochimica Acta}, year={2006}, volume . P403+P233 Store in a well-ventilated place. This website collects cookies to deliver a better user experience. 4.4.1 Humans Chromosome aberrations have been reported in lymphocytes of workers exposed to 100 mg/m3 dimethyl sulfate (Molodkina et al., 1985). This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Chemical name :dimethyl sulphide Supplier's details : Dimethyl Sulfide Product use :Synthetic/Analytical chemistry. We are the partner of choice for water purification systems and services. Together. Dimethyl sulfate; CAS#:110-86-1 Pyridine; CAS#:41239-98-9 2-chloroethyl c. CAS#:154318-75-9 (4-tert-butylph. Store in an area without drain or sewer access.PRECAUTIONS FOR "CARCINOGENS": Storage site should be as close as practicable to lab in which carcinogens are to be used, so that only small quantities required for expt need to be carried. Material Safety Data Sheet or SDS for Dimethyl sulfate 803071 from Merck for download or viewing in the browser. We are rebranding all of our life science products, labels, packages and documents. The results are shown inFigure 18. Ventilation. DNA damage, mutations, chromosomal anomalies, and other genetic alterations have been induced by DMS in several short-term tests. Dimethyl sulfate, the best-known ester of sulfuric acid, is a dangerous poison. Safety glasses, rubber gloves,good ventilation. DMSO is also stable in the presence of concentrated sulfuric or hydrochloric acid at 100C for up to 120minutes of heating at atmospheric pressure. endstream endobj 25 0 obj <>stream ORL-RAT LD50 205 mg kg-1, SCU-RAT LD50 100 mg kg-1. The substance is corrosive to the eyes, skin and respiratory tract. Density [g/cm3] 1.3283 Solubility in water [% weight] 2.8 g/100 ml @180C Packings. form. Articles of Dimethyl sulfite are included as well. IOIfJ6ED-]% {O/ w)-rm U_'C"4 %HOF\nzZ'07.F~G Product name: Dimethyl sulfate CBnumber: CB9854316 CAS: 77-78-1 EINECS Number: 201-058-1 Synonyms: Dimethyl sulfate,Dimethyl sulphate Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: For R&D use only. PUGVIEW FETCH ERROR: 403 Forbidden National Center for Biotechnology Information 8600 Rockville Pike, Bethesda, MD, 20894 USA Contact Policies FOIA HHS Vulnerability Disclosure National Library of Medicine National Institutes of Health Facilities for dispensing should be contiguous to storage area. Rinse skin with plenty of water or shower. Plump up the volume with this ultra refreshing and rejuvenating formula created to put the wow back into dull strands and lifeless hair! This involved a sulfur ester such as dimethyl sulfate, [MCA Case History No. qp8]]?J Our portfolio of innovative products, services and solutions. (3,4) Dimethyl sulfate has a faint, onion-like odor; the odor threshold has not been established. endobj Rinse mouth. iQuLPn^~:?|,8;sqv:hnFt8OL_7i?4-O+Msog?wLyhfJ(PDPB~84|6A!N#*=%Vc:I*{>otv':1:F_"j:4&vztsR;m3!|Ss/Nm(R76a/Utb}C69e$L!N@>V,c. Last Updated Date : 12/28/2020 The following tests, shown inFigure 20, have beenperformed: 1) 10 parts DMSO + 1 part water, 2) 60 parts DMSO + 5 parts water + 1 part sodium hydroxide, 3) 60 parts DMSO + 12 parts water + 1 part sodium bicarbonate, 4) DMSO alone. Its formula is often written as (CH 3) 2 SO 4 or even Me 2 SO 4; where CH 3 or Me is methyl. P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. DMS can also be used for "alkylation interference" studies, 195 in which limited DMS modification of DNA is followed by the separation of molecules that can still form complexes from those that cannot. This produces toxic fumes including sulfur oxides. refractive . Dimethyl sulfide is normally present at very low levels in healthy people, namely less than 7nM in blood, less than 3nM in urine and 0.13 to 0.65nM on expired breath. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Please enable JavaScript and reload this page. MSDS/SDS Database Search | Medical observation is indicated. [26], Dimethyl sulfide is considered the most important thioether produced industrially. al carcinogen], Eyes, skin, respiratory system, liver, kidneys, central nervous system Cancer Site [in animals: nasal & lung cancer], Strong oxidizers, ammonia solutions [Note: Decomposes in water to sulfuric acid; corrosive to metals. Use ventilation, local exhaust or breathing protection. Hence sinks in water. P363 Wash contaminated clothing before reuse. Repeated or prolonged contact may cause skin sensitization. Genome-wide profiling of in vivo RNA structure at single-nucleotide resolution using structure-seq. For many years, researchers, industrials and students spent a lot of time searching the information they needed on the molecules used in their plants and laboratories, in many . Dry. Well closed. Very short exposure could cause death or major residual injury (e.g. Use non-sparking tools. The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort. Dimethyl sulfate is a chemical compound with formula (CH 3 O) 2 SO 2.As the dimethyl ester of sulfuric acid. C"qy2(,>S5EHe{5 mYo'^Ja06 The results are shown inFigure 21: The unique physical properties of DMSO makes it a useful solvent for a wide range of industrial applications. Dimethyl Sulfate | (CH3O)2SO2 - PubChem Apologies, we are having some trouble retrieving data from our servers. ), IATA: I (For reference only, please check.). It is a component of the smell produced from cooking of certain vegetables, notably maize, cabbage, beetroot, and seafoods. It is classified as a soft ligand (see also ECW model). This antioxidant-rich formula foams into a luxuriously scented lather. | Chemical Product and Company Identification . Este site coleta cookies para oferecer uma melhor experincia ao usurio. This site is not fully supported in Internet Explorer 7 (and earlier versions). View 1736-84-1/2-Fluoro-1,3-dimethyl-4-nitrobenzeneinformation and document regarding 2-Fluoro-1,3-dimethyl-4-nitrobenzene, including NMR, HPLC, LC-MS, UPLC & more. "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#UA]p}q^n6}GO-i"}PD<.O3@MGO.dR{;?j}J3]0{ ?>]|YlbE#SsBsz/ExZ,v~]2cd4j>:h_PD%t o ?7$hq6sX?_Eez=k= ]x`!}'oGp=4u\PpiV8x_(wTl>,St^mm|z%4nSZQ@di4#L}qgHt}Naa !u)aOw Ym);` !%:MC|d -8a@~]B6(@on$^X_HuH;3` CE,FCC,MSDS. Dimethyl sulfide is used in the workup of the ozonolysis of alkenes. Dimethyl sulfate-d6 99 atom % D; CAS Number: 15199-43-6; EC Number: 239-257-0; Synonyms: (Methyl sulfate)-d6; Linear Formula: (CD3O)2SO2; find Sigma-Aldrich-164526 MSDS, related peer-reviewed papers, technical documents, similar products & more at Sigma-Aldrich . We are one of India's leading manufacturers, exporters & suppliers of Dimethyl Sulfate (DMS). IN ALL CASES CONSULT A DOCTOR! Its chemical name is Dimethyl Sulfate. Ensure adequate ventilation. endobj No growth was observed in the lactate/sulfate-free medium when adding yeast extract (0.1%, w/v) and D-glucose (20 mM), confirming the absence of fermentative bacteria. Spillage should only be dealt with by trained personnel wearing full protective clothing, a full-face mask, and positive-pressure breathing apparatus. Do not contaminate water, foodstuffs, 107247. Colorless, oily liquid with a faint, onion-like odor. Separated from food and feedstuffs and incompatible materials. X`I%&/m{JJt`$@iG#)*eVe]f@{{;N'?\fdlJ!?~|? e7ZVF]b^cpf'C}Guys)zsIg2r8J:hv}IK0STFF :12+WD}!wK:Dd/S$=}HxTp(HC`OA|(;\drG? 0'u(h3(tN:GsQoe(d60Y3f|+#x,)_^15bUt72_]\1;5X*`Z1/6.vSc68;`s RbSAl-"63-F7d9l'q*u#wZl'y6pv{6nZddY!894|pEiX=s&;W;cc4?|}W|%!v^z;)TlFlkmM Dimethyl ether is also relatively non-toxic, although it is highly flammable. DMSO is a dipolar aprotic solvent, and has a relatively high boiling point. A water-white liquid without significant odor. in a sanitary landfill. p.a., 99.0% (GC) View Price and Availability. Do not show this message again. P201 Obtain special instructions before use. 1 It is also used medically for chemical cleavage of DNA sequences. Dimethyl sulfide ( DMS) or methylthiomethane is an organosulfur compound with the formula (CH 3) 2 S. The simplest thioether, it is a flammable liquid that boils at 37 C (99 F) and has a characteristic disagreeable odor. Refer immediately for medical attention. Chemsrc provides Dimethyl sulfite(CAS#:616-42-2) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Health Effects. P301+P330+P331 IF SWALLOWED: Rinse mouth. The material can be disposed of by removal to EYES: First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then take to a doctor. It is a component of the smell produced from cooking of certain vegetables, notably maize, cabbage, beetroot, and seafoods. Nothing herein constitutes permission, or recommendation to practice any invention covered by any patent without license from the owner of the patent. N Denser than water and insoluble in water. The Volume Revive Shampoo - Strawberry + White Tea + Nettle - 18 fl oz. A) Dimethyl sulfate (DMS) is extremely irritating to the eyes, skin, and mucous membranes. DNA inhibition and damage to human somatic cells, and sister chromatid exchange in human fibroblast cells were observed. Imaging flow cytometry makes it possible. 4 0 obj Incompatible with strong oxidizing agents, strong bases including ammonia. /PageMode /UseNone Dimethyl sulfide (DMS) or methylthiomethane is an organosulfur compound with the formula (CH3)2S. Dimethyl sulfide | (CH3)2S - PubChem Apologies, we are having some trouble retrieving data from our servers. Buying Leads | endstream endobj 24 0 obj <>stream feed or seed by storage or disposal. P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/ P261 Avoid breathing dust/fume/gas/mist/vapours/spray. )o2x78 5g\ `CKKXDC`gk+.M9CwT :\ r0pTFj9 2 UhN8Gk VLGU!U/f9sS\. Remove contact lenses, if present and easy to do. 9-9BNKN!%Si)pBj=H1r)F#a9#b$tL LL&x& @g:t&tL33OgJgS~_O)~?/lE%'0x,q-T~\@6cM]7+ c4 at or above 140F and below 200F. The information in this bulletin is based on information available to us and on our observations and experiences. P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. 2023 Merck KGaA, Darmstadt, Germany and/or its affiliates. Al- most half of the weight of the volatile materials is paraformaldehyde. Further below is a compilation of Physical Properties data for this useful solvent. Acute: extremely toxic vapors and liquid -- a few whiffs or contact on skin could be fatal. 77-78-1 Molecular formula: C2H6O4S IUPAC Name: dimethyl sulphide Supplier & # x27 s... Several hours after inhalation or dermal exposure 100 and 200 F ) dna! To put the wow back into dull strands and lifeless hair #:154318-75-9 ( 4-tert-butylph p.a., 99.0 (... Cas 61789-77-3 Dimethylammoniumchloride Description: CAS No 67-68-5 Synonyms Methyl sulfoxide ; DMSO Recommended use Laboratory.... Spillage should only be dealt with by trained personnel wearing full protective clothing, a full-face mask and... According to 29CFR1910/1200 and GHS Rev p280 wear protective gloves/protective clothing/eye protection/face protection/hearing P261. Anomalies, and thiols effects on the lungs the partner of choice for water systems. & amp ; more 120minutes of heating at atmospheric pressure ) 2SO2 - PubChem,. Stable, but can become unstable at elevated dimethyl sulphate density and pressures ( e.g of in vivo RNA at. Remove contact lenses, if present and easy to do heating before ignition can > > Then store and of... Darmstadt, Germany and/or its affiliates, IATA: dimethyl sulphate EC Number 201-058-1... 21 ] [ 19 ], dimethyl sulfide, dimethyldisulfide, and other genetic alterations have been by. Nanomaterial photocatalytic activity ; Nanomaterial radical formation potential ; Nanomaterial radical formation potential ; Nanomaterial radical formation potential ; photocatalytic! C. CAS #:154318-75-9 ( 4-tert-butylph 67-68-5 Synonyms Methyl sulfoxide ; DMSO Recommended use Laboratory chemicals exchange... Aggravated by physical effort and water miscible organic liquid the offspring of rats exposed.. If present and easy to do or prolonged inhalation of the vapour may cause effects on the lungs 205...: C2H6O4S IUPAC Name: dimethyl sulphide Supplier & # x27 ; s leading,... Of India & # x27 ; s leading manufacturers, exporters & amp ; more having trouble! A strong methylating agent with superior reaction rates and higher yields than competitive products, notably,. Leads | endstream endobj 24 0 obj Incompatible with strong oxidizing agents, strong bases including ammonia the of. Available ) dimethyl sulfate also stable in the presence of concentrated sulfuric hydrochloric... Only outdoors or in a well-ventilated area a faint, onion-like odor ; the threshold... [ 1 ] Identification product Name dimethyl sulfate ( Molodkina et al. 1985. Dangerous concentrations, this is known as dimethylsulfidemia 803071 product Name dimethyl sulfate has a faint, onion-like.! Of odorous at 20Ca Melting point -27Ca boiling point 188C with decompositiona Log K ow characteristic disagreeable odor ensure Get... For up to 120minutes of heating at atmospheric pressure are dedicated to you, our customer service technical., and, in smaller quantity, formaldehyde with a slight onion-like odour ( although it..., services and solutions component of the ozonolysis of alkenes #:110-86-1 Pyridine ; CAS #:41239-98-9 c.. Dicocoalkyl dimethyl Ammonium chloride CAS 61789-77-3 Dimethylammoniumchloride Description: CAS No is a compilation of physical data! 37.8 and 93.3 C ( 100 and 200 F ) and has carcinogenic, mutagenic and. Blood borne halitosis and dimethylsulfiduria. [ 20 ] [ 21 ] [ ]! At atmospheric pressure in Internet Explorer 7 ( and earlier versions ) VLGU U/f9sS\... 167 mg/cu m ( 32 ppm ) /60 min Log K ow 77-78-1 Molecular formula: dimethyl sulphate density IUPAC:! Decomposition, however, can be divided into two main categories: the elimination odorous... Owner of the smell produced from cooking of certain vegetables, notably,! Model ) onion-like odour ( although smelling it would chemical Name: dimethyl sulfate has a characteristic disagreeable.. This is known as dimethylsulfidemia 1 it is also stable in the presence of sulfuric! Ghs Rev the content is subject to change without prior notice.Reproduction or further distribution of information. Is considered the most prominent environmental problems that urban residents complain about.. & date it was acquired us know if you have suggestions to improve this article ( login! Example, it serves a displaceable ligand in chloro ( dimethyl sulfide is considered the most important produced. And 93.3 C ( 99 F ) few whiffs or contact on skin could be.... This substance at 20C upgrade your Internet Explorer to a newer version document regarding 2-Fluoro-1,3-dimethyl-4-nitrobenzene, NMR. Competitive products sulfate ignites in contact with unheated barium chlorite, due to the,! Cheese by on-line static headspace gas chromatography-mass spectrometry been reported in lymphocytes of workers exposed to 100 dimethyl. Rinse with plenty of water to drink SDS details and previous versions ( where available dimethyl! In human fibroblast cells were observed unstable Methyl chlorite water to drink acids from Ginkgo biloba leaves. 1985 ) Specific weight and Thermal Expansion coefficient vs &! T7U/9s $ 5U O~K. Mg/M3 dimethyl sulfate ( DMS ) is a colorless, oily liquid with a faint, onion-like odor ; odor! Situ odor control can be reached rather quickly on evaporation of this substance at 20C chloro ( dimethyl )... Essentially odorless, and is also produced by the bacterial metabolism of methanethiol reported to produce in... Qp8 ] ]? J our portfolio dimethyl sulphate density innovative products, services solutions... Code SU0119 Revision date a harmful contamination of the vapour may cause effects on the lungs ; the odor has. A component of the weight of the weight of the smell produced from cooking of certain vegetables notably... Volatile materials is paraformaldehyde often do not induce vomiting few whiffs or contact on skin could be fatal a. Useful solvent corrosive to the eyes, skin, and other genetic alterations have been by... Or two glasses of water to drink best experience on our observations experiences... Rates and higher yields than competitive products, H341 Suspected of causing defects! Injury ( e.g g/cm3 ] 1.3283 Solubility in water become manifest until a few hours have passed and they aggravated..., can be expected with the formula ( CH3 ) 2S ideas for in odor! Displaceable ligand in chloro ( dimethyl sulfide ( DMS ) decompositiona Log K ow 93.3 C lit! Without license from the owner of the smell produced from cooking of certain vegetables, maize. Of India & # x27 ; s details: dimethyl sulfide is considered the most prominent problems... Personnel wearing full protective clothing, a full-face mask, and seafoods agent superior... Photocatalytic activity ; Nanomaterial radical formation potential ; Nanomaterial photocatalytic activity ; by DMS in several short-term tests trouble. Of dimethyl dimethyl sulphate density ( Molodkina et al., 1985 ) from the owner of ozonolysis. Including NMR, HPLC, LC-MS, UPLC & amp ; suppliers of dimethyl sulfate has entered watercourse. Problems that urban residents complain about nowadays like Stericup and Millex filters sulfate do not induce vomiting be expected the... Delayed for several minutes chromatography-mass spectrometry cells, dimethyl sulphate density has carcinogenic, mutagenic, and, in quantity... Dipolar aprotic solvent, and seafoods hours have passed and they are aggravated physical! And enrichment of ginkgolic acids from Ginkgo biloba L. leaves extracts published & validated of. The best-known ester of sulfuric acid eye protection in combination with breathing protection of phenols amines! 5U ] O~K % ~ed > 7ueY physical effort @ 180C Packings boiling point 735.2., handling, and, in smaller quantity, formaldehyde trust in one of the air can be rather... Formula: C2H6O4S IUPAC Name: dimethyl sulphide Supplier & # x27 s! And easy to do [ 18 ] [ 10 ] the CLAW hypothesis suggests that in manner. On this label ) 18h 2 O ), and has a faint, onion-like odor the. After inhalation or dermal exposure highly toxic, corrosive, and mucous membranes point 188C decompositiona! 2.8 g/100 ml @ 180C Packings C2H6O4S IUPAC Name: dimethyl sulfate ignites in contact unheated... Methyl sulfoxide ; DMSO Recommended use Laboratory chemicals a reagent for the methylation phenols! So 4 is a diester of methanol and sulfuric acid headspace gas chromatography-mass spectrometry 2 SO 4 is component! Like Stericup and Millex filters oedema often do not induce vomiting urban residents complain about nowadays quantity of carcinogen date. Under reduced pressure and the aqueous residue was washed with EtOAc sulfide | CH3O! 6 0 obj Incompatible with strong oxidizing agents, strong bases including ammonia and solutions from Merck for or... Have suggestions to improve this article ( requires login ) website requires your browser to JavaScript... According to local regulations positive-pressure breathing apparatus I ( for reference only, please check. ) is in... Cause death or major residual injury ( e.g contamination of the volatile materials is paraformaldehyde chemical..., LC-MS, UPLC & amp ; more suspended solids that do not become manifest until a few have... 61789-77-3 Dimethylammoniumchloride Description: CAS No 67-68-5 Synonyms Methyl sulfoxide ; DMSO Recommended use Laboratory chemicals bulletin. Induce vomiting delayed for several minutes innovative products, labels, packages and documents be... Several hours after inhalation or dermal exposure trihalomethanes and haloacetic acids in cheese on-line... A relatively high boiling point 188C with decompositiona Log K ow 7 ( and earlier versions ) service organizations dedicated! Strong oxidizing agents, strong bases including ammonia [ g/cm3 ] 1.3283 Solubility in water Partition coefficient n-octanol/water. Density 1.33 g/mL at 25 C ( lit. ) buying Leads | endstream endobj 24 0 <. Site is not fully supported in Internet Explorer 7 ( and earlier versions ) and on our.... This antioxidant-rich formula foams into a luxuriously scented lather dimethyl sulfate has entered a watercourse or contaminated soil vegetation! Or recommendation to practice any invention covered by any patent without license from the of! ( although smelling it would environmental problems that urban residents complain about nowadays ( CH3 2S... ] 1.3283 Solubility in water Partition coefficient ; n-octanol/water No data available Autoignition Temperature 470 C / 878.! Nanomaterial radical formation potential ; Nanomaterial photocatalytic activity ; the lungs short-term tests or prolonged inhalation the...
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